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Later still, Viper, alongside numerous other snake-inspired costumed villains, infiltrated the criminal organization known as the Serpent Society with the intent of taking it over. Soon after, Viper and the Silver Samurai clashed with the New Mutants when they attempted to coerce the motorcycle stunt riding Team America into stealing the Cavorite crystal. She blamed Spider-Woman for this violation of her mind, and tried to seek revenge.
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This entire scenario was later revealed to be false when Viper broke free of the hypnotic blocks placed in her mind by le Fey. The elder god wanted to use Spider-Woman to emerge on Earth, but Viper ultimately defied Chthon, with the help of the force of will of Spider-Woman, who resisted Chthon long enough for Viper to ultimately free herself from his thrall. Hoping to unravel the mysteries of her origin, Spider-Woman tracked Viper down to confront her and was tossed into this dimension and seemingly forced to confront Chthon. Morgan sought to use the Viper as a weapon against Spider-Woman and briefly replaced the Viper's right eye with a black orb capable of projecting others into a magical dimension. Viper, under the influence of Morgan le Fey, believed herself to be Meriem Drew, Spider-Woman's mother. Viper battled Spider-Woman when Drew stumbled onto one of Viper's plots during her career as a private investigator in San Francisco. Viper next organized her own terrorist cell and employed the mutant warrior the Silver Samurai as her bodyguard. Acquiring the ancient and powerful Serpent Crown artifact, she sought world domination but was again opposed by Captain America. She reorganized the then-defunct Serpent Squad, killing the original costumed criminal Viper, taking his alias. Madame Hydra eventually returned from Limbo after the Phantom ceased using her form, but was on the outs with Hydra due to his actions.
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However, her identity was stolen by the Space Phantom, who turned her branch of Hydra into his own private army. Taking the name Madame Hydra, she took control of their New York operations and frequently clashed with the super-soldier Captain America. Seraph died, but not before making Wolverine swear an oath of loyalty to Viper. Later, Viper and Seraph rescued another pupil, the mutant adventurer Wolverine, from his arch-nemesis, the feral mutant Sabretooth. For a time she became a mercenary and then a pupil of the adventurer Seraph on the island nation of Madripoor.